Vesicle Morphogenesis in Amphiphilic Triblock Copolymer Solutions

May 6, 2024·
Senyuan Liu
,
Mohammad Sadegh Samie
,
Radhakrishna Sureshkumar
· 1 min read
Schematic of the published vesicle-formation pathway.
Abstract
Coarse-grained molecular dynamics simulations are used to study vesicle formation in amphiphilic BAB triblock copolymer solutions. The work follows the morphology pathway from initially dispersed polymers through interconnected aggregates, cylindrical micelle cages, lamellar cages, and finally closed vesicles, connecting molecular reorganization and chain conformations to the emerging self-assembled structures.
Type
Publication
Colloids and Interfaces, 8(3), 29
publications

This paper examines how amphiphilic BAB triblock copolymers self-assemble into vesicles in aqueous solution. The simulations reveal a pathway through a transient interconnected aggregate network, a cage of cylindrical micelles, and a lamellar cage before vesicle closure.

Authors
PhD Candidate in Biomedical and Chemical Engineering
I am a PhD candidate in Biomedical and Chemical Engineering at Syracuse University, advised by Prof. Radhakrishna Sureshkumar and co-advised by Prof. James Henderson. My research uses coarse-grained molecular dynamics to study polymer and surfactant self-assembly, with a focus on amphiphilic copolymer systems, micelles, vesicles, and the molecular mechanisms that drive morphology evolution.