Vesicle Morphogenesis in Amphiphilic Triblock Copolymer Solutions

May 6, 2024·
Senyuan Liu
,
Mohammad Sadegh Samie
,
Radhakrishna Sureshkumar
· 1 min read
Abstract
Coarse-grained molecular dynamics simulations are used to study vesicle formation in amphiphilic BAB triblock copolymer solutions. The work follows the morphology pathway from initially dispersed polymers through interconnected aggregates, cylindrical micelle cages, lamellar cages, and finally closed vesicles, connecting molecular reorganization and chain conformations to the emerging self-assembled structures.
Type
Publication
Colloids and Interfaces, 8(3), 29
publications

This paper examines how amphiphilic BAB triblock copolymers self-assemble into vesicles in aqueous solution. The simulations reveal a pathway through transient aggregate networks, cage-like cylindrical micelle structures, and lamellar shells before vesicle closure.

Authors
PhD Student in Biomedical and Chemical Engineering
I am a PhD student in Biomedical and Chemical Engineering at Syracuse University, where my primary adviser and PI is Dr. Radhakrishna Sureshkumar and my co-adviser is Dr. James Henderson. My research uses coarse-grained molecular dynamics to study polymer and surfactant self-assembly, with a focus on amphiphilic copolymer systems, micelles, vesicles, and the molecular mechanisms that drive morphology evolution.